Adsorption of phenol from aqueous solution onto Luffa Cylindrica Cords: equilibrium, kinetic, and thermodynamic

Y. Laidani, G. Henini, S. Hanini, A. Fekaouni

Abstract


Abstract: The results obtained show that Luffa cylindrica cords / phenol have an adsorption capacity (qm=2.54 mg/g). The adsorption process was rapid and reached equilibrium in 25 min of contact at 23 °C and pH 8.5. The different adsorption models Langmuir, Freundlich, Temkin and Elovich were used for the mathematical description of the adsorption equilibrium, and it was found that the very well - equipped experimental data for the Langmuir model (R2=0.994), the pseudo - first - order and pseudo - second - order kinetic models were applied to the experimental data. The experimental data fitted very well the pseudo-second-order kinetic model (R2= 0.999) and also followed the model of intra particle diffusion (Kdif vary from 0.125 to 0.374 mg/g.min1/2 for concentrations between 10 and 100 mg/L), whereas diffusion is not the only rate - control step. Finally the thermodynamic constants of adsorption phenomena, ∆H° and ∆S° were found to be -6.219 kJ/mol and -0.019 kJ/mol.K in the range of 3 – 23 °C respectively. The negative value of the Gibbs free energy ∆G° demonstrates the spontaneous nature of phenol adsorption onto Luffa cylindrica cords.

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Khemmari, F.; Benrachedi, K. A comparative study of raw and treated peach stones for the adsorption of hexavalent chromium: characterization, kinetic and thermodynamic modelling. Algerian Journal of Environmental Science and Technology 4 (2) (2018) 762-770.

Khenniche, L.; Benissad-Aissani, F. Adsorptive Removal of Phenol by Coffee Residue Activated Carbon and Commercial Activated Carbon: Equilibrium, Kinetics, and Thermodynamics. Jounal Chemical Engineering Data 55 (2010) 4677-4686.

Lin, S.-H.; Juang, R.-S. Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents. a review, Journal of Environmental Management 90(3) (2009) 1336-1349.

Lazo-Cannata, J.C.; Nieto-Marquez, A.; Jacobyetal, A.. Adsorption of phenol and nitrophenols by carbon nanospheres: effect of pH and ionic strength. Separation and Purification Technology 80(2) (2011) 217-224.

Yahia cherif, L.; Aissani-Benissad, F. Adsorption of phenol onto activated carbon prepared from coffee extract residue chemically activated using ZnCl2. Algerian Journal of Environmental Science and Technology 2(1) (2016) 22-32.

Mohd-Din, A. T.; Hameed, B.H. ; Ahmad, A.L. Batch adsorption of phenol onto physiochemical-activated coconut shell. Journal of Hazardous Materials. 161(2-3, (2009) 1522-1529.

Desmiarti, R.; Trianda, Y.; Martynis, M. ; Viqri, A.; Yamada, T.; Li, F. Phenol adsorption in water by granular activated carbon from coconut shell. International Journal of Technology. 10(8) (2019). 1488-1497.

Dursun, G.; Ciçek, H.; Dursun, A.Y. Adsorption of phenol from aqueous solution by using carbonised beet pulp. Journal of Hazardous Materials B125 (2005) 175-182.

Ildefonso, B.N.; Jorge, S.A.; Angel, G.D.; Alvaro, R.J. Removal and Biodegradation of Phenol by the Freshwater Microalgae Chlorella Vulgaris. Contemporary Engineering Sciences 11(40) (2018) 1961 - 1970.

Sonawane Bhausaheb, K.; Korake, S.R. Removal of phenol from wastewater using low cost adsorbent. International Journal of Science, Engineering and Technology Research 5(6) (2016) 2249-2253.

Henini, G.; Laidani, Y.; Souahi, F.; Hanini, S. Study of static adsorption system phenol / Luffa cylindrica fiber for industrial treatment of wastewater. Energy Procedia 18 (2012) 395-403.

Abdelwahab, O.; Amin, N.K. Adsorption of phenol from aqueous solutions by Luffa cylindrica fibers: Kinetics, isotherm and thermodynamic studies. Egyptian Journal of Aquatic Research 39 (2013), 215-223.

Laidani, Y.; Hanini, S.; Mortha, G.; Henini, G. Study of a Fibrous Annual Plant, Luffa Cylindrica for Ppaper Application Part I: Characterization of the Vegetal. Iranian Journal of Chemistry and Chemical Engineering 31(4) (2012) 119-129.

Gupta, V.K.; Agarwal, S.; Singh, P.; Pathania, D. Acrylic acid grafted cellulosic Luffa cylindrical fiber for the removal of dye and metal ions. Carbohydrate Polymers 98 (2013) 1214-1221.

Tanobe, V.O.A.; Sydenstricker, T.H.D., Munaro,M., Amico,S.C., “A comprehensive characterization of chemically treated Brazilian sponge-gourds (Luffa cylindrica) Polym. Test. 24 (2005) 474–482.

Demir, H.; Top, A.; Balkose, D.; Ulku, S. Dye adsorption behaviour of Luffa cylindrical fibers. Journal of Hazardous Materials 153 (2008) 389-394.

Nadavala, S.K.; Kim, M.N. Removal of phenolic compounds from aqueous solutions by biosorption onto acacia leucocephala bark powder: equilibrium and kinetic studies. Journal Chilean Chemical Society 56(1) (2011).

Ma, Y.; Gao, N.; Chu, W.; Li, C. Removal of phenol by powdered activated carbon adsorption. Frontiers of Environmental Science & Engineering 7(2) (2013) 158–165.

Cherifi, H.; Hanini, S.; Bentahar, F. Adsorption of phenol from wastewater using vegetal cords as a new adsorbent. Desalination 244 (2009) 177–187.

Afsharnia, M.; Saeidi, M.; Zarei, A.; Reza, M.; Narooie, M.; Biglari, H. Phenol removal from aqueous environment by adsorption onto pomegranate peel carbon. Electronic Physician 8(11) (2016) 3248-3256.

Aksu, Z.; Karabayir, G. Comparison of biosorption properties of different kinds of fungi for the removal of Gryfalan Black RL metal-complex dye. Bioresource Technology 9 (2008) 7730-7741.

Hameed, B.H.; Rahman, A.A. Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material. Journal of Hazardous Materials 160 (2008) 576–581.

Mohebali, S.; Bastani, D.; Shayesteh, H. Methylene blue removal using modified celery (Apium graveolens) as a low-cost biosorbent in batch mode: Kinetic, equilibrium, and thermodynamic studies. Journal Molecular. Structural 1173 (2018) 541-551.

Akpen, G. D.; Aho, M. I.; Mamwan, M.H. Equilibrium and Kinetics of Colour Adsorption from Textile Wastewater by a Novel Adsorbent. Global Journal of Pure and Applied Sciences 24 (2018) 61-67.

Malakootian, M.; Askarpour, A.; Amirmahani, N.; Nasiri, Z.; Nasir, ARemoval of Hexavalent Chromium from Aqueous Solutions Using Magnetic Nanoparticles Coated with Alumina and Modified by Cetyl Trimethyl Ammonium Bromide. Journal of Community Health Research 4(3) .(2015) 177-193.

Dehvari, M.; Ehrampoush, M.; Ghaneian, H.; Taghi, M. Adsorption Kinetics and Equilibrium Studies of Reactive Red 198 Dye by Cuttlefish Bone Powder. Iranian Journal of Chemistry and Chemical Engineering 36(2) (2017) 143-151.

Haq Nawaz, B.; Rubina, K.; Muhammad Asif, H. Biosorption of Pb (II) and Co (II) on Red Rose Waste Biomass. Iranian Journal of Chemistry and Chemical Engineering 30(4) (2011) 81-87.

Beigi, S.M.; Babapoor, A.; Maghsoodi, V.; Mousavi, S.M.; Rajabi, N. Batch Equilibrium and Kinetics Studies of Cd (II) Ion Removal from Aqueous Solution Using Porous Chitosan Hydrogel Beads. Iranian Journal of Chemistry and Chemical Engineering 28(3) (2009) 81-89.

Xu, H.; Liu, D.; He, L.; Liu, N.; Ning, G. Adsorption of Copper (II) from an Wastewater Effluent of Electroplating Industry by Poly (ethylenediamine) - Functionalized Silica. Iranian Journal of Chemistry and Chemical Engineering 34(2) (2015) 73-81.

Seo-Hui, P.; Jin-Hyun, K. Isotherm, Kinetic, and Thermodynamic Characteristics for Adsorption of 2,5-Xylenol onto Activated Carbon. Biotechnology and Bioprocess Engineering 23 (2018) 541-549.

Çiriğ Selçuk, N.; Kubilay, Ş.; Savran, A.; Rıza Kul, A. Kinetics and Thermodynamic Studies of Adsorption of Methylene Blue from Aqueous Solutions onto Paliurus spina-christi Mill. Frutis and Seeds. OSR Journal of Applied Chemistry 10(I) (2017) 53-63.

Zhang, J.; Stanforth, R. Slow Adsorption Reaction between Arsenic Species and Goethite (α-FeOOH): Diffusion or Heterogeneous Surface Reaction Control. Langmuir 21(7) (2005) 2895-2901.

Almeida, C.A.P.; Debacher, N.A.; Downsc, A.J.; Cottet, L.; Mello, C.A.D. Removal of Methylene Blue from Colored Effluents by Adsorption on Montmorillonite Clay. Journal of Colloid and Interface Science 332 (2009) 46-53.

El Gaidoumi, A.; Chaouni Benabdallah, A.; Lahrichi, A.; Kherbeche, A. Adsorption of Phenol in Aqueous Medium by a Raw and Treated Moroccan Pyrophyllite. Journal of Materials and Environmental Science 6 (8) (2015) 2247-2259.

Leong, KY.; Adnan, R.; Lim, PE.; Ng, SL.; Seng, CE. Effect of operational factors on bioregeneration of binary phenol and 4- chlorophenol-loaded granular activated carbon using PVA immobilized biomass cryogels. Environmental Science Pollution Research 24(26) (2017) 20959-20971.

Makhlouf, M.; Hamacha, R.; Villièras, F.; Bengueddach, A. Kinetics and thermodynamics adsorption of phenolic compounds on organic-inorganic hybrid mesoporous material. International Journal of Innovation and Applied Studies 3(4) (2013) 1116-1124.

Uddin, M.T.; Islam, M.S.; Abedin, M.Z. Adsorption of phenol from aqueous solution by water hyacinth ash. Journal of Engineering and Applied Sciences 2(2) (2007), 11-17.

Dhidan, S.K. Removal of phenolic compunds from aqueous solutions by adsoption onto activted carbons prepared from date stones by chemical activation with FeCl3. Journal of engineering 1(18) (2012) 63 – 77.

Srivastava, V.C.; Swamy, M.M.; Mall, I.D.; Prasad, B.; Mishra, I.M. Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics. Colloids Surface A: Physicochemical Engineering Aspects 27 (2006) 289–104.

Lagergren, S. Zur Theorie Der Sogenannten Adsorption Gelöster Stoffe, Kungliga Svenska. Vetenskapsakademiens, 4th edition, Handlingar Vol 24 (1898) 1-39.

Elmouwahidi, A.; Bailón-García, E.; Pérez-Cadenas, A.F.; Maldonado-Hódar, F.J.; Carrasco-Marín, F. Activated carbons from KOH and H3PO4- activation of olive residues and its application as supercapacitor electrodes. Electrochimic Acta, 229 (2017) 219-228.

Weber, J.R.; Morris, J.C. Kinetics of Adsorption on Carbon from Solution. Journal of the Sanitary Engineering Division 89(2) (1963) 31-60.

Kayode, O. A.; Bamidele, I.O.; Emmanuel, C.C. Removal of Safranin-O from Aqueous Solution by Adsorption onto Kaolinite Clay. Journal of Encapsulation and Adsorption Sciences 4 (2014) 89-104.

Gundogdu, A; Duran, C.; Basri Senturk, H.; Soylak, M.; Ozdes, H.; Imamoglu, M. Adsorption of Phenol from Aqueous Solution on a Low-Cost Activated Carbon Produced from Tea Industry Waste: Equilibrium, Kinetic, and Thermodynamic Study. Journal of Chemical and Engineering Data 57 (2012) 2733−2743.

Goto, M.; Hayashi, N.; Goto, S. Adsorption and desorption of phenol on anion-exchange resin and activated carbon. Environmental Science Technology 20 (1986) 463-467.

Bouhamed, F.; Elouear, Z.; Bouzid, J. Adsorptive removal of copper(II) from aqueous solutions on activated carbon prepared from Tunisian date stones: Equilibrium, kinetics and thermodynamics. Journal of the Taiwan Institute of Chemical Engineers 43 (2012) 741-749.

Seki, Y.; Yurdakoc, K. Adsorption of Promethazine Hydrochloride with KSF Montmorillonite. Adsorption 12(1) (2006) 90-100.

Yuh-Shan, Ho.; Augustine, E.; Fomaja, O. Kinetics and Thermodynamics of Lead Ion Sorption on Palm Kernel Fibre from Aqueous Solution. Process Biochemistry 40 (2005) 3455-3461.

Senthil Kumar, P.; Gayathri, R. Adsorption of Pb2+ Ions from Aqueous Solutions onto Bael Tree Leaf Powder: Isotherms, Kinetics and Thermodynamics Study.Journal of Engineering Science and Technology 4(4) (2009) 381-399.

Henini, G.; Laidani, Y.; Souahi, F.; Labbaci, A; Hanini, S. Equilibrium, Kinetic and Thermodynamic Studies of the Biosorption of Textile Dye (Yellow Bemacid) onto Brahea edulis. International Journal of Materials and Textile Engineering, 10(7) (2016) 931-937.

Alkan, M.; Demirbaş, Ö.; Celikcapa, S.; Doğan, M. Sorption of acid red 57 from aqueous solution onto sepiolite. Journal of Hazardous Materials, 116(1) (2004) 135-145.

Fu, Q.L.; Deng, Y.L.; Li, H.S.; Liu, J.; Hua, H.Q.;Chen, S.W.; Sa, T.M. Equilibrium, kinetic and thermodynamic studies on the adsorption of the toxins of Bacillus thuringiensis subsp. kurstaki by clay minerals. Applied Surface Science 255 (2009) 4551-4557.

Canizares, P.; Carmona, M.; Baraza, O.; Delgado, A.; Rodrigo, M.A. Adsorption equilibrium of phenol onto chemically modified activated carbon F400. Journal of Hazardous Materials 131 (2006) 243-248.


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